| Stamicarbon and Sandvik have developed a new duplex stainless
steel material, which does not require the high concentration
of oxygen in the process streams to maintain a passive layer.
Laboratory corrosion tests never resulted in active corrosion
even under conditions that oxygen concentrations were possibly
zero. This material has been named Safurex®.
The use of Safurex® as construction material
in the urea synthesis made Stamicarbon decide that the oxygen
content in the CO2 can be safely reduced to below
0.04% (vol.).
The passivation air is therefore minimized. Consequently the
chance that during upset plant conditions the inert vent gas
from the synthesis section becomes flammable is now almost
non existing and makes the plant intrinsically safe.
The use of Safurex® as construction material
in urea plants is becoming more and more common and Stamicarbon
has since 2001 made it its standard. Fabrication of urea synthesis
equipment is experienced as easy. The corrosion resistance
of the material is better than the corrosion resistance of
the traditional urea quality stainless steels. The resistance
of Safurex® against stress corrosion cracking
due to Chlorides in tubes of the traditional HP carbamate
condensers is far better than experienced with austenitic
materials, which are sensitive for stress corrosion cracking.
The investment in Safurex® equipment is below
the investment in equipment using traditional materials. All
equipment and parts needed for a complete grass roots urea
plant in Safurex® are commercially available.
Investment
Safurex® has a significantly higher mechanical
strength than the austenitic stainless steels traditionally
used in urea plants. This property allows designers to reduce
the thickness of liner plates, tube walls in heat exchangers
and HP pipe wall thickness while maintaining even better life
time expectations of the equipment.
The overall investment costs of Safurex® equipment,
as a consequence of this increased material strength, is lower
than the costs of traditional equipment (about 5 to 10%).
Besides the above, the reduction in tube wall thickness results
in a larger inner diameter of the heat exchanger tube, which
in turn has an impact on the dimensions and finally the weight
of the equipment.
Availability of Safurex®
To be able to reduce the oxygen concentration in the CO2
to zero, the synthesis section must be constructed completely
in Safurex®. Therefore, besides plates, bar,
tubes, pipe, weld consumables and the like, also check valves,
safety valves, block valves and control valves in contact
with the process medium are available in Safurex®
too.
Stamicarbon and Sandvik have solved the availability
topics with a number of suppliers of these parts, resulting
in proper and competitive availability of these materials.
As Safurex® has been developed by Sandvik together
with Stamicarbon, the material is principally available for
use in projects using the Stamicarbon urea technology.
For more information you can download the Safurex
® paper [ 1810
kb].
Experience
Increasing numbers of customers choose Safurex®
for their newly built equipment and piping as evidenced by
the growing list of references. Several high pressure carbamate
condensers and strippers as well as complete synthesis equipment
and piping have been delivered.
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